The side will be playing against current HSBC World Sevens series leaders, New Zealand in the first quarterfinal.
Samoa remained undefeated in their pool stage after beating Spain 35-15 in their last pool game.
New Zealand lost their last pool game after they were beaten 17-14, going down to a late South Africa penalty shot at goal after both sides had scored two tries.
The quarterfinal match between Samoa and New Zealand will kick start at 9.37pm.