She alleged Jonas Junius, 22, had grabbed her and tried to kiss her. She also accused him of offering her money to have sex.
Junius is competing in the light-welterweight division.
Last week, a Moroccan boxer was arrested by police after allegedly assaulting two female cleaners.
A Brazilian judge has ordered Hassan Saada to be detained for 15 days, pending an investigation, media reports said.
This could mean Saada is unable to take part in the Games.