Samoa’s tries came from Peter Mata'utia, Jarome Luai, Young Tonumaipe'a, Ken Maumalo and Suaia Matagi.
Joesph Leilua added to tha tally with his two tries.
The conversions came from Matthew Wright, Fa'amanu Brown and Joseph Paulo.
There were two tries for NSW Country U23’s from Jacob Gagai and a try each from Ryley Thomas, Kyle Krisanski-Kennedy and Jack Hickson.
The clash is the first for Toa Samoa since its line up for the RLWC was announced last week.
Toa Samoa’s campaign for the RLWC kicks off against New Zealand in Auckland on 28 October.